Molecular modulation of nickel–salophen organic frameworks enables the selective photoreduction of CO<sub>2</sub>at varying concentrations

Authors: Xiaohan Yu, Mingzi Sun, Tianran Yan, Lin Jia, Mingyu Chu, Liang Zhang, Wei Huang, Bolong Huang, Yanguang Li

Published: 2024-02-06

DOI: 10.1039/d3ee04121b

Source: Full article


Abstract

Metal–salophen organic frameworks with dispersed metal centers and precise coordination environments were synthesized. The optimal sample exhibited great photocatalytic activity and near-unity CO selectivity over a wide range of CO2concentrations.