Bis(trimethylsilyl)phosphide chemistry: a half-century of advances across the periodic table

Authors: Jack Baldwin, David P. Mills

Published: 2025-03-12

DOI: 10.1039/d4cs01141d

Source: Full article

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Abstract

We review structurally authenticated metal(loid) bis(trimethylsilyl)phosphide complexes, highlighting how their solid-state structures and electronic structures differ from those containing the related bis(trimethylsilyl)amide ligand.