Recent advances in catalytic asymmetric metalloid–hydrogen bond insertion of transition-metal carbenes

Authors: Shuyue Zhang, Ming-Hua Xu

Published: 2025-06-09

DOI: 10.1039/d5cs00195a

Source: Full article

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Abstract

This review provides an overview of recent progress and advances in transition-metal-catalyzed asymmetric carbene insertion into metalloid–hydrogen bonds (B–H/Si–H/Ge–H), emphasizing ligand design, mechanistic studies, and synthetic applications.