Selective UV Sensing for Energy‐Efficient UV‐A Artificial Synapses Using a ZnO/ZnGa<sub>2</sub>O<sub>4</sub> Heterojunction Diode

Authors: Taslim Khan, Santanu Kandar, Sazid Ali, Pushpapraj Singh, Ray‐Hua Horng, Rajendra Singh

Published: 2025-03-12

DOI: 10.1002/smll.202500098

Source: Full article


Abstract

AbstractAs neuromorphic computing systems, which allow for parallel data storage and processing with high area and energy efficiency, show great potential for future storage and in‐memory computing technologies. In this article, a high‐performance UV detector for artificial optical synapse applications is demonstrated that can selectively detect UV‐A and UV‐C, with a responsivity of 407 A W−1. The pyrophototronic effect increases photocurrent dramatically under UV‐A irradiation due to heat accumulation in the ZnO layer and ZnGa2O4’s low thermal conductivity. In context of synaptic device, it's shown that a ZnO/ZnGa2O4 heterostructure can be used as a light‐tunable charge trapping medium to create an electro‐photoactive synapse. The photogating effect enables via pyrophototronic, which traps photogenerated electrons within the ZnO/ZnGa2O4 interface, and drives synaptic activity, as proven by electrical techniques based on UV‐A stimuli. This phenomenon results in a selective detection capability for UV‐A over UV‐C. Thermally produced pyrophototronic effect synaptic plasticity, simulating biological synapse activity. Persistent photoconductivity under 380 (UV‐A) nm UV light mimics synaptic processes, with low thermal conductivity enhancing synaptic weight updates during learning and forgetting. These findings show the possibility of using ZnO/ZnGa2O4 heterostructures into artificial optoelectronic synapse systems controlled by thermal dynamics.