Authors: Xiangming Xu, Jasmin Smajic, Kuang‐hui Li, Jung‐Wook Min, Yongjiu Lei, Bambar Davaasuren, Xin He, Xixiang Zhang, Boon S. Ooi, Pedro M. F. J. Costa, Husam N. Alshareef
Published: 2021-11-11
Source: Full article
AbstractThe ability to control lattice orientation is often an essential requirement in the growth of both 2D van der Waals (vdW) layered and nonlayered thin films. Here, a unique and universal phenomenon termed “lattice orientation heredity” (LOH) is reported. LOH enables product films (including 2D‐layered materials) to inherit the lattice orientation from reactant films in a chemical conversion process, excluding the requirement on the substrate lattice order. The process universality is demonstrated by investigating the lattice transformations in the carbonization, nitridation, and sulfurization of epitaxial MoO2, ZnO, and In2O3 thin films. Their resultant compounds all inherit the mono‐oriented crystal feature from their precursor oxides, including 2D vdW‐layered semiconductors (e.g., MoS2), metallic films (e.g., MXene‐like Mo2C and MoN), wide‐bandgap semiconductors (e.g., hexagonal ZnS), and ferroelectric semiconductors (e.g., In2S3). Using LOH‐grown MoN as a seeding layer, mono‐oriented GaN is achieved on an amorphous quartz substrate. The LOH process presents a universal strategy capable of growing epitaxial thin films (including 2D vdW‐layered materials) not only on single‐crystalline but also on noncrystalline substrates.