Correlation-driven attosecond photoemission delay in the plasmonic excitation of C

Authors: Shubhadeep Biswas, Andrea Trabattoni, Philipp Rupp, Maia Magrakvelidze, Mohamed El-Amine Madjet, Umberto De Giovannini, Mattea C. Castrovilli, Mara Galli, Qingcao Liu, Erik P. Månsson, Johannes Schötz, Vincent Wanie, Pawel Wnuk, Lorenzo Colaizzi, Daniele Mocci, Maurizio Reduzzi, Matteo Lucchini, Mauro Nisoli, Angel Rubio, Himadri S. Chakraborty, Matthias F. Kling, Francesca Calegari

Published: 2025-02-12

DOI: 10.1126/sciadv.ads0494

Source: Full article


Abstract

Extreme light confinement in plasmonic nanosystems enables novel applications in photonics, sensor technology, energy harvesting, biology, and quantum information processing. Fullerenes represent an extreme case for nanoplasmonics: They are subnanometer carbon-based molecules showing high-energy and ultrabroad plasmon resonances; however, the fundamental mechanisms driving the plasmonic response and the corresponding collective electron dynamics are still elusive. Here, we uncover the dominant role of electron correlations in the dynamics of the giant plasmon resonance (GPR) of the subnanometer system C